Printed zinc tin oxide diodes: from combustion synthesis to large-scale manufacturing

نویسندگان

چکیده

Abstract Printed metal oxide devices have been widely desired in flexible electronic applications to allow direct integration on foils and reduce waste associated costs. Especially, semiconductor made from non-critical raw materials, such as Zn, Sn (and not, for example, In), gained significant interest. Despite considerable progress the field, upscale requirements lab fab scale produce these materials remain a challenge. In this work, we report importance of solution combustion synthesis (SCS) when compared with sol–gel production zinc tin (ZTO) thin films using solvent (1-methoxypropanol) that has lower environmental impact than used toxic 2-methoxyethanol. To assure compatibility low-cost substrates high-throughput printing techniques, low annealing temperature 140 °C was achieved by combining SCS infrared short processing time. These conditions allowed transition spin-coating (lab scale) flexographic (fab at speed 10 m min −1 roll-to-roll pilot line. The ZTO (1:1 Zn:Sn-ratio) diodes show rectification ratio 3 , operation voltage (⩽3 V), promising reproducibility variability. results provide basis further optimisation (device size, encapsulation) meet electronics passive-matrix addressing, energy harvesting rectification.

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ژورنال

عنوان ژورنال: Flexible and printed electronics

سال: 2022

ISSN: ['2058-8585']

DOI: https://doi.org/10.1088/2058-8585/ac4bb1